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Abstract Many sub-Neptune and super-Earth exoplanets are expected to develop metal-enriched atmospheres due to atmospheric loss processes such as photoevaporation or core-powered mass loss. Thermochemical equilibrium calculations predict that at high metallicity and a temperature range of 300–700 K, CO₂becomes the dominant carbon species, and graphite may be the thermodynamically favored condensate under low-pressure conditions. Building on prior laboratory findings that such environments yield organic haze rather than graphite, we measured the transmittance spectra of organic haze analogs and graphite samples and computed their optical constants across the measured wavelength range from 0.4 to 25μm. The organic haze exhibits strong vibrational absorption bands, notably at 3.0, 4.5, and 6.0μm, while graphite shows featureless broadband absorption. The derived optical constants of haze and graphite provide the first data set for organic haze analogs formed in CO₂-rich atmospheres and offer improved applicability over prior graphite data derived from bulk reflectance or ellipsometry. We implemented these optical constants into the Virga and PICASO cloud and radiative transfer models to simulate transit spectra for GJ 1214b. The synthetic spectra with organic hazes reproduce the muted spectral features in the near-infrared observed by Hubble and general trends observed by JWST for GJ 1214b, while graphite models yield flat spectra across the observed wavelengths. This suggests haze features may serve as observational markers of carbon-rich atmospheres, whereas graphite’s opacity could lead to radius overestimation, offering a possible explanation for superpuff exoplanets. Our work supplies essential optical to infrared data for interpreting observations of CO₂-rich exoplanet atmospheres. 

Abstract Super-Earths and sub-Neptunes are the most common exoplanets, with a “radius valley” suggesting that super-Earths may form by shedding sub-Neptunes’ gaseous envelopes. Exoplanets that lie closer to the super-Earth side of the valley are more likely to have lost a significant fraction of their original H/He envelopes and become enriched in heavier elements, with CO₂gaining in abundance. It remains unclear which types of haze would form in such atmospheres, potentially significantly affecting spectroscopic observations. To investigate this, we performed laboratory simulations of two CO₂-rich gas mixtures (with 2000 times solar metallicity at 300 and 500 K). We found that under plasma irradiation organic hazes were produced at both temperatures, with a higher haze production rate at 300 K, probably because condensation occurs more readily at lower temperature. Gas-phase analysis demonstrates the formation of various hydrocarbons, oxygen- and nitrogen-containing species, including reactive gas precursors like C₂H₄, CH₂O, and HCN, for haze formation. The compositional analysis of the haze particles reveals various functional groups and molecular formulas in both samples. The 500 K haze sample has larger average molecular sizes, a higher degree of unsaturation with more double or triple bonds present, and higher nitrogen content incorporated as N–H and C=N bonds, indicating different haze formation pathways. These findings not only improve the haze formation theories in CO₂-rich exoplanet atmospheres but also offer important implications for the interpretation of future observational data. 

Abstract The recent inference of sulfur dioxide (SO₂) in the atmosphere of the hot (approximately 1,100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations^1–3suggests that photochemistry is a key process in high-temperature exoplanet atmospheres⁴. This is because of the low (<1 ppb) abundance of SO₂under thermochemical equilibrium compared with that produced from the photochemistry of H₂O and H₂S (1–10 ppm)^4–9. However, the SO₂inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 μm and, therefore, the detection of other SO₂absorption bands at different wavelengths is needed to better constrain the SO₂abundance. Here we report the detection of SO₂spectral features at 7.7 and 8.5 μm in the 5–12-μm transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS)¹⁰. Our observations suggest an abundance of SO₂of 0.5–25 ppm (1σrange), consistent with previous findings⁴. As well as SO₂, we find broad water-vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 μm. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy-element content (metallicity) for WASP-39b of approximately 7.1–8.0 times solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range. 

Abstract The unprecedented medium-resolution (R_λ∼ 1500–3500) near- and mid-infrared (1–18μm) spectrum provided by JWST for the young (140 ± 20 Myr) low-mass (12–20M_Jup) L–T transition (L7) companion VHS 1256 b gives access to a catalog of molecular absorptions. In this study, we present a comprehensive analysis of this data set utilizing a forward-modeling approach applying our Bayesian framework,ForMoSA. We explore five distinct atmospheric models to assess their performance in estimating key atmospheric parameters:T_eff, log(g), [M/H], C/O,γ,f_sed, andR. Our findings reveal that each parameter’s estimate is significantly influenced by factors such as the wavelength range considered and the model chosen for the fit. This is attributed to systematic errors in the models and their challenges in accurately replicating the complex atmospheric structure of VHS 1256 b, notably the complexity of its clouds and dust distribution. To propagate the impact of these systematic uncertainties on our atmospheric property estimates, we introduce innovative fitting methodologies based on independent fits performed on different spectral windows. We finally derived aT_effconsistent with the spectral type of the target, considering its young age, which is confirmed by our estimate of log(g). Despite the exceptional data quality, attaining robust estimates for chemical abundances [M/H] and C/O, often employed as indicators of formation history, remains challenging. Nevertheless, the pioneering case of JWST’s data for VHS 1256 b has paved the way for future acquisitions of substellar spectra that will be systematically analyzed to directly compare the properties of these objects and correct the systematics in the models. 

Abstract We present a performance analysis for the aperture masking interferometry (AMI) mode on board the James Webb Space Telescope Near Infrared Imager and Slitless Spectrograph (JWST/NIRISS). Thanks to self-calibrating observables, AMI accesses inner working angles down to and even within the classical diffraction limit. The scientific potential of this mode has recently been demonstrated by the Early Release Science (ERS) 1386 program with a deep search for close-in companions in the HIP 65426 exoplanetary system. As part of ERS 1386, we use the same data set to explore the random, static, and calibration errors of NIRISS AMI observables. We compare the observed noise properties and achievable contrast to theoretical predictions. We explore possible sources of calibration errors and show that differences in charge migration between the observations of HIP 65426 and point-spread function calibration stars can account for the achieved contrast curves. Lastly, we use self-calibration tests to demonstrate that with adequate calibration NIRISS F380M AMI can reach contrast levels of ∼9–10 mag at ≳λ/D. These tests lead us to observation planning recommendations and strongly motivate future studies aimed at producing sophisticated calibration strategies taking these systematic effects into account. This will unlock the unprecedented capabilities of JWST/NIRISS AMI, with sensitivity to significantly colder, lower-mass exoplanets than lower-contrast ground-based AMI setups, at orbital separations inaccessible to JWST coronagraphy. 

Abstract Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability¹. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program^2,3found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO₂) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M_J) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. ⁴). The most plausible way of generating SO₂in such an atmosphere is through photochemical processes^5,6. Here we show that the SO₂distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations⁷with NIRSpec PRISM (2.7σ)⁸and G395H (4.5σ)⁹. SO₂is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H₂S) is destroyed. The sensitivity of the SO₂feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO₂also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations. 

Abstract The Saturn-mass exoplanet WASP-39b has been the subject of extensive efforts to determine its atmospheric properties using transmission spectroscopy^1–4. However, these efforts have been hampered by modelling degeneracies between composition and cloud properties that are caused by limited data quality^5–9. Here we present the transmission spectrum of WASP-39b obtained using the Single-Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument on the JWST. This spectrum spans 0.6–2.8 μm in wavelength and shows several water-absorption bands, the potassium resonance doublet and signatures of clouds. The precision and broad wavelength coverage of NIRISS/SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favouring a heavy-element enhancement (‘metallicity’) of about 10–30 times the solar value, a sub-solar carbon-to-oxygen (C/O) ratio and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are also best explained by wavelength-dependent, non-grey clouds with inhomogeneous coverageof the planet’s terminator. 

Abstract We present JWST Early Release Science coronagraphic observations of the super-Jupiter exoplanet, HIP 65426b, with the Near-Infrared Camera (NIRCam) from 2 to 5μm, and with the Mid-Infrared Instrument (MIRI) from 11 to 16μm. At a separation of ∼0.″82 (87 ${}_{-31}^{+108}$au), HIP 65426b is clearly detected in all seven of our observational filters, representing the first images of an exoplanet to be obtained by JWST, and the first-ever direct detection of an exoplanet beyond 5μm. These observations demonstrate that JWST is exceeding its nominal predicted performance by up to a factor of 10, depending on separation and subtraction method, with measured 5σcontrast limits of ∼1 × 10⁻⁵and ∼2 × 10⁻⁴at 1″ for NIRCam at 4.4μm and MIRI at 11.3μm, respectively. These contrast limits provide sensitivity to sub-Jupiter companions with masses as low as 0.3M_Jupbeyond separations of ∼100 au. Together with existing ground-based near-infrared data, the JWST photometry are fit well by aBT-SETTLatmospheric model from 1 to 16μm, and they span ∼97% of HIP 65426b's luminous range. Independent of the choice of model atmosphere, we measure an empirical bolometric luminosity that is tightly constrained between $\log \left(L_{\mathrm{bol}}/L_{\odot }\right)$= −4.31 and −4.14, which in turn provides a robust mass constraint of 7.1 ± 1.2M_Jup. In totality, these observations confirm that JWST presents a powerful and exciting opportunity to characterize the population of exoplanets amenable to high-contrast imaging in greater detail. 

Abstract Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems^1,2. Access to the chemical inventory of an exoplanet requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based^3–5and high-resolution ground-based^6–8facilities. Here we report the medium-resolution (R ≈ 600) transmission spectrum of an exoplanet atmosphere between 3 and 5 μm covering several absorption features for the Saturn-mass exoplanet WASP-39b (ref. ⁹), obtained with the Near Infrared Spectrograph (NIRSpec) G395H grating of JWST. Our observations achieve 1.46 times photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO₂(28.5σ) and H₂O (21.5σ), and identify SO₂as the source of absorption at 4.1 μm (4.8σ). Best-fit atmospheric models range between 3 and 10 times solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO₂, underscore the importance of characterizing the chemistry in exoplanet atmospheres and showcase NIRSpec G395H as an excellent mode for time-series observations over this critical wavelength range¹⁰. 

Abstract Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy (for example, refs.^1,2) provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution and high precision, which, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST’s Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0–4.0 micrometres, exhibit minimal systematics and reveal well defined molecular absorption features in the planet’s spectrum. Specifically, we detect gaseous water in the atmosphere and place an upper limit on the abundance of methane. The otherwise prominent carbon dioxide feature at 2.8 micrometres is largely masked by water. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1–100-times solar (that is, an enrichment of elements heavier than helium relative to the Sun) and a substellar C/O ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation (for example, refs.^3,4,) or disequilibrium processes in the upper atmosphere (for example, refs.^5,6).